Power-based Fuels and Chemicals
The subtopic addresses the conversion of the low-energy molecules CO2, H2O and N2 with renewable electrical energy as well as renewable or waste heat into high-energy chemical fuels and feedstocks for industry. This way the subtopic will contribute to a defossilization of the transport sector and the industrial sector. The CO2 may originate from different sources which are jointly evaluated together with researchers from Topic 5. Given the desired reduction of the anthropogenic CO2 emissions, thin air or waste biomass are preferred choices. However, CO2 from unavoidable industrial sources such as cement production, steel making, and waste incineration is considered as well. We strive for advancing the scientific knowledge in catalysis, electrocatalysis and plasma chemistry both with a view to activation of CO2, H2O and N2 and efficient catalytic processes for synthesis of high-quality fuels and chemicals from its products. The scope includes high-temperature mixed ionic-electronic conductor (MIEC)-based ceramic membrane reactors, which hold potential for improving various conversion steps. Catalytic technologies for the loading and unloading of liquid organic hydrogen carriers (LOHCs) and a direct use of hydrogenated LOHCs in fuel cells are in focus as well. High-performing catalysts and electrocatalysts showing high activity and selectivity and long lifetime even under dynamic load are targeted. Similarly, highly permeable and stable membranes are pursued.
Simple, efficient and reliable process technologies, capable of dynamic operation will be developed, scaled-up, and demonstrated on system level in real technical environments together with key partners from industry and society. Special emphasis is on intensified process technologies with modular design. Disruptive approaches to the fabrication of compact process units will be taken, e.g. additive manufacturing, to achieve high performance, reliability in operation, and cost-effective digitized fabrication. The scope includes the design and study of entire power-to-molecules process chains with vast integration of material and heat flows between process units to achieve a high overall energy efficiency. Both solutions for large-scale implementation and compact systems for decentralized applications will be pursued where operational flexibility is needed in addition to high efficiency and acceptable cost. The subtopic strives for rapid implementation of modular power-to-molecules technologies with high technology readiness level (TRL) by teaming up with innovative industrial partners. Two spin-off companies INERATEC GmbH (KIT) and Hydrogenious Technologies GmbH (University of Erlangen-Nürnberg) as well as other visionary start-up’s and their allies are key partners for commercialization. At the same time, high-risk approaches at lower TRLs with high potential gain will be fundamentally investigated and purposefully further developed.
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Generic paths for synthesis of fuels & chemicals
Main themes are...
- Modular integrated plants
- Conversion of CO/CO2-rich syngas
- Direct electrochemical synthesis (Electocatalysis beyond hydrogen)
- Plasma reactors / Plasma activation of inert molecules
- H2-Safety of decentralized modular plants
- Technologies for LOHC - Liquid organic hydrogen carriers
We work in the above six thematic groups. This enables scientific exchange and joint cooperation across institutes and Helmholtz centers. To strengthen networking between the Helmholtz partners, joint workshops are held regularly.
Selected Projects | Project Archive
We engage in collaborative research projects with academic & industrial partners. Thus, we transfer knowledge into application, strengthen networking & talent management.
Electroorganic synthesis - from research to industry: IAM-ET: Joint pool of electrode materials and electrolysis cells (Pool Mazel); IMVT: Development and analysis of a large-scale electrolyzer for long-term operation (EAGLE); BMBF website, KIT-news
https://zukunftscluster-etos.de/UP-TO-ME is an EU funded project that targets a ground-breaking change in decentralised Power-to-Methanol production for hard to electrify applications, like marine vessels. Grant number: 101083323
https://up-to-me.com/Synthesis of model catalysts and operando characterization methods. Basic energy research (BMBF) Grant: 03SF0673B; Partner: KIT IKFT, HZB, FH IKTS, Sasol Germany, INERATEC, KIT IIP, R&D Center FH Kiel
Care-O-SENE website3D printing laboratory & Fischer Tropsch synthesis plant
What are the processes & technologies to produce chemicals without fossil sources but with renewable energies? Sharing progress and scientific challenges in our research program.
Read moreAssessing the role of Direct Air Capture in a carbon neutral world: The workshop shall establish a basic understanding of the major DAC technologies and their differences...
Helmholtz-Workshop: July 2, 2021
aims to present the scope of research in our different groups, share both knowledge & experiences and initiate opportunities for networking & co-operation between Helmholtz Centers.
Transfer of Knowledge and Technology
We share and transfer knowledge and technology to the public, experts, politics, administration and the business world.
7 May 2021: Nanocat's role & potentials for CO2 savings & energy efficiency was discussed in the workshop of the Research Network Energy with stakeholders of the innovation system: academia, industry, associations, and policymakers.
Modular chemical plants for Gas-to-Liquid, Power-to-Gas & Power-to-Liquid processes producing CO2 neutral fuels for mobility, storage of "green" energy & decentralized production of chemicals: INERATEC
Twitter@INERATEC_globalThe objective of the project is to identify key innovations of energy-efficient solutions and to network them in their different application areas within the BMWi Research Network Energy.
EE4InG websiteWorkshop of industry, science & policy makers about innovative products & technical solutions reducing energy consumption & CO2 emissions.
EE4InG websiteWe offer girls from 8th grade onwards exciting insights into our work & labs: Fuels from air & green energy @IMVT, H2 a sustainable energy storage @ITCP/IKFT, Battery empty?! @BTC
more@Girls' Day RadarPublications
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Shirsath, A. B.; Mokashi, M.; Pashminehazar, R.; Çelik, A.; Lott, P.; Tischer, S.; Grunwaldt, J.-D.; Deutschmann, O.
Investigating the formation of soot in CH4 pyrolysis reactor: A numerical, experimental, and characterization study
2025. Carbon, 231, Art.-Nr.: 119689. doi:10.1016/j.carbon.2024.119689
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Tountas, A. A.; Dreher, A.; Zhou, W.; Mohan, A.; Kherani, N. P.; Ozin, G. A.; Sain, M. M.
Light-harvesting properties of photocatalyst supports—no photon left behind
2024. npj Computational Materials, 10 (1), Art.-Nr.: 239. doi:10.1038/s41524-024-01409-0 -
Heikkinen, N.; Dhamo, D.; Uotila, I.; Reinikainen, M.; Dittmeyer, R.
Production of C₂ −C₄ Olefins with Fischer‐Tropsch‐Synthesis: The Effect of Cu Promoter Loading on an Fe−Cu−K/SiO₂ Catalyst
2024. ChemCatChem, 16 (19), e202400560. doi:10.1002/cctc.202400560 -
Pan, X.; Cheng, Q.; Gu, X.; Jiang, Y.; Wang, Z.; Hua, M.; Xiao, J.; Jordan, T.; Jiang, J.
Research on the flow characteristics and self-ignition mechanism of high-pressure hydrogen jets in bifurcated tubes
2024. Process Safety and Environmental Protection, 188, 1191–1200. doi:10.1016/j.psep.2024.06.004 -
Siegert, F.; Gundermann, M.; Maurer, L.; Hahn, S.; Hofmann, J.; Distel, M.; Schühle, J.; Müller, K.; Wolf, M.; Preuster, P.; Auer, F.; Geißelbrecht, M.; Wasserscheid, P.
Autothermal hydrogen release from liquid organic hydrogen carrier systems
2024. International Journal of Hydrogen Energy, 91, 834–842. doi:10.1016/j.ijhydene.2024.10.044 -
Biffar, L.; Pham, A. T.; Benzinger, W.; Pfeifer, P.
Performance of a RuCs/MgO catalyst coated on additive manufactured support structures via electrophoretic deposition for ammonia synthesis
2024. Chemical Engineering and Processing - Process Intensification, 205, Art.-Nr.: 110019. doi:10.1016/j.cep.2024.110019 -
Mahmoudizadeh, M.; Klahn, C.; Dittmeyer, R.
Powder bed fusion of solid and permeable Crofer 22 APU parts for applications in chemical process engineering
2024. Progress in Additive Manufacturing. doi:10.1007/s40964-024-00811-w -
Rui, S.; Xiao, J.; Wang, C.; Wang, F.; Kuznetsov, M.; Jordan, T.
Numerical study of external explosion in vented hydrogen explosions
2024. Process Safety and Environmental Protection, 191 (A), 1516–1533. doi:10.1016/j.psep.2024.09.022 -
Mockenhaupt, B.; Gieser, J.; Najafishirtari, S.; Baumgarten, L.; Jelic, J.; Lunkenbein, T.; Ras, E.-J.; Grunwaldt, J.-D.; Studt, F.; Behrens, M.
On the secondary promotion effect of Al and Ga on Cu/ZnO methanol synthesis catalysts
2024. Journal of Catalysis, 439, Art.-Nr.: 115785. doi:10.1016/j.jcat.2024.115785 -
Mokashi, M.; Shirsath, A. B.; Demir, S.; Çelik, A.; Lott, P.; Tischer, S.; Deutschmann, O.
Kinetics of thermal dry reforming of methane for syngas production and solid carbon capture
2024. Reaction Chemistry & Engineering, 9 (11), 2902–2914. doi:10.1039/d4re00312h -
Paripsa, S.; Gaur, A.; Förste, F.; Doronkin, D. E.; Malzer, W.; Schlesiger, C.; Kanngießer, B.; Welter, E.; Grunwaldt, J.-D.; Lützenkirchen-Hecht, D.
RefXAS: an open access database of X-ray absorption spectra
2024. Journal of Synchrotron Radiation, 31 (5), 1105–1117. doi:10.1107/S1600577524006751 -
Das, S.; Kahnt, M.; van Valen, Y.; Bergh, T.; Blomberg, S.; Lyubomirskiy, M.; Schroer, C. G.; Venvik, H. J.; Sheppard, T. L.
Restructuring of Ag catalysts for methanol to formaldehyde conversion studied using in situ X-ray ptychography and electron microscopy
2024. Catalysis Science & Technology, 14 (20), 5885–5898. doi:10.1039/D4CY00770K -
Chowdhury, A. G.; Arnold, U.; Garbev, K.; Bender, M.; Sauer, J.
Direct dehydrogenation of methanol to formaldehyde over ZnO–SiO -based catalysts
2024. Catalysis Science and Technology, 14 (17), 4958–4967. doi:10.1039/D4CY00541D -
Zhou, S.; Xiao, J.; Luo, Z.; Kuznetsov, M.; Chen, Z.; Jordan, T.; Banuti, D. T.
Analysis of spontaneous ignition of hydrogen-enriched methane in a rectangular tube
2024. Proceedings of the Combustion Institute, 40 (1-4), 105681. doi:10.1016/j.proci.2024.105681 -
Guse, D.; Warmuth, L.; Herfet, M.; Adolf, K.; Zevaco, T. A.; Pitter, S.; Kind, M.
Seeding as a Decisive Tool for Increasing Space-Time-Yields in the Preparation of High-Quality Cu/ZnO/ZrO₂ Catalysts
2024. Catalysts, 14 (8), Article no: 517. doi:10.3390/catal14080517 -
Mahayni, Y.; Maurer, L.; Auer, F.; Hutzler, A.; Wasserscheid, P.; Wolf, M.
Structure sensitivity of the low temperature dehydrogenation of perhydro (di)benzyltoluene on supported platinum nanoparticles
2024. Catalysis Science & Technology, 14 (18), 5464–5473. doi:10.1039/D4CY00032C -
Weber, S.; Karpov, D.; Kahnt, M.; Diaz, A.; Romanenko, Y.; Kotrel, S.; Haas, A.; Hinrichsen, B.; Bottke, N.; Grunwaldt, J.-D.; Schunk, S.; Sheppard, T. L.
Multimodal Hard X‐ray Nanotomography Probes Pore Accessibility of Technical Catalysts after Coking
2024. ChemCatChem, e202301298. doi:10.1002/cctc.202301298 -
Maurer, L. A.; Pham, C. v.; Fritsch, B.; Jeppesen, H. S.; Etter, M.; Hutzler, A.; Neder, R. B.; Wolf, M.; Auer, F.; Thiele, S.; Wasserscheid, P.
Improving Hydrogen Release From Oxygen‐Functionalized LOHC Molecules by Ru Addition to Pt/C Catalysts
2024. ChemCatChem, e202400375. doi:10.1002/cctc.202400375 -
Bäuerle, M.; Paintner, T.; Schmolke, D.; Systermans, T.; Kinnen, W.; Jordan, T.
H ‐Transport‐ und Speicheroptionen: Normen und technische Regeln. Das Projekt TransHyDE‐Norm – Normen für den Transport von Wasserstoff nach und in Deutschland
2024. Chemie Ingenieur Technik, 96 (1-2), 211–219. doi:10.1002/cite.202300145 -
Otroshchenko, T.; Sharapa, D. I.; Fedorova, E. A.; Zhao, D.; Kondratenko, E. V.
Highly Efficient Low‐loaded PdOx/AlSiOx for Ethylene Dimerization
2024. Angewandte Chemie International Edition, 63 (44), e202410646. doi:10.1002/anie.202410646 -
Hübner, J. L.; Lucchetti, L. E. B.; Nong, H. N.; Sharapa, D. I.; Paul, B.; Kroschel, M.; Kang, J.; Teschner, D.; Behrens, S.; Studt, F.; Knop-Gericke, A.; Siahrostami, S.; Strasser, P.
Cation Effects on the Acidic Oxygen Reduction Reaction at Carbon Surfaces
2024. ACS Energy Letters, 9 (4), 1331–1338. doi:10.1021/acsenergylett.3c02743 -
Gietzelt, T.; Walter, M.; Toth, V.; Messerschmidt, F.
On the suitability of alloys with a high molybdenum content ...for the manufacture of corrosion-resistant microprocessing equipment by diffusion welding - Part 1 of 2. Corrosion aspects, materials and corrosion and diffusion welding tests; [über die Eignung von hoch molybdänhaltigen Legierungen]
2024. Galvanotechnik, 115 (6), 742 – 749 -
Borchers, M.; Förster, J.; Thrän, D.; Beck, S.; Thoni, T.; Korte, K.; Gawel, E.; Markus, T.; Schaller, R.; Rhoden, I.; Chi, Y.; Dahmen, N.; Dittmeyer, R.; Dolch, T.; Dold, C.; Herbst, M.; Heß, D.; Kalhori, A.; Koop-Jakobsen, K.; Li, Z.; Oschlies, A.; Reusch, T. B. H.; Sachs, T.; Schmidt-Hattenberger, C.; Stevenson, A.; Wu, J.; Yeates, C.; Mengis, N.
A Comprehensive Assessment of Carbon Dioxide Removal Options for Germany
2024. Earth’s Future, 12 (5), e2023EF003986. doi:10.1029/2023EF003986 -
Daga, M.; Sanna, C.; Bais, G.; Polentarutti, M.; Massardo, S.; Carnasciali, M.; Holtappels, P.; Costamagna, P.; Pani, M.; Artini, C.
Impact of the electrospinning synthesis route on the structural and electrocatalytic features of the LSCF (La0.6Sr0.4Co0.2Fe0.8O3–δ) perovskite for application in solid oxide fuel cells
2024. Solid State Ionics, 413, Art.-Nr.: 116620. doi:10.1016/j.ssi.2024.116620 -
Sarma, B. B.; Neukum, D.; Doronkin, D. E.; Lakshmi Nilayam, A. R.; Baumgarten, L.; Krause, B.; Grunwaldt, J.-D.
Understanding the role of supported Rh atoms and clusters during hydroformylation and CO hydrogenation reactions with in situ / operando XAS and DRIFT spectroscopy
2024. Chemical Science, 15 (31), 12369–12379. doi:10.1039/D4SC02907K -
Braun, L.; Spielmann, J.; Doronkin, D. E.; Kuhn, C.; Maliugin, A.; Sharapa, D. I.; Huck, I.; Bao, J.; Tischer, S.; Studt, F.; Deutschmann, O.; Kramm, U. I.; Grunwaldt, J.-D.
Following the Structural Changes of Iron Oxides during Reduction under Transient Conditions
2024. ChemSusChem, Art.-Nr.: e202401045. doi:10.1002/cssc.202401045 -
Grosselindemann, C.; Dorn, M.; Bauer, F. M.; Seim, M.; Ewald, D.; Esau, D.; Geörg, M.; Rössler, R.; Pundt, A.; Weber, A.
Pressurized single cell testing of solid oxide cells
2024. Journal of Power Sources, 614, Art.-Nr.: 234963. doi:10.1016/j.jpowsour.2024.234963 -
Treu, P.; Gonçalves, D.; Lakshmi Nilayam, A. R.; Grunwaldt, J.-D.; Saraçi, E.
One‐pot cascade reaction from epoxide to carboxylic acids using bifunctional Fe‐ZSM‐5
2024. ChemCatChem, 16 (20), Art.-Nr.: 202400626. doi:10.1002/cctc.202400626 -
Rex, A.; Almeida De Campos, L.; Gottschalk, T.; Ferreira Sanchez, D.; Trinke, P.; Czioska, S.; Saraçi, E.; Bensmann, B.; Grunwaldt, J.-D.; Hanke-Rauschenbach, R.; Sheppard, T. L.
Elemental Distribution in Catalyst‐Coated Membranes of Proton Exchange Membrane Water Electrolysers Tracked by Synchrotron X‐Ray Fluorescence
2024. Advanced Energy and Sustainability Research, 5 (9), Art.-Nr.: 2400048. doi:10.1002/aesr.202400048 -
Hecimovic, A.; Mayer, M. T.; de Haart, L. G. J.; Gupta, S.; Kiefer, C. K.; Navarrete, A.; Schulz, A.; Fantz, U.
Benchmarking microwave-induced CO plasma splitting against electrochemical CO reduction for a comparison of promising technologies
2024. Journal of CO2 Utilization, 83, Art.-Nr.: 102825. doi:10.1016/j.jcou.2024.102825 -
Li, J.; Šimek Tosino, H.; Ladewig, B. P.; Jung, N.; Bräse, S.; Dittmeyer, R.
Extraction of the intrinsic rate constant for a photocyclization reaction in capillary microreactors using a simplified reactor model
2024. Reaction Chemistry & Engineering, 9 (8), 2149–2159. doi:10.1039/d4re00087k -
Rybakov, K. I.; Mahmoud, M. M.; Link, G.
Analysis of microwave heating of copper powder compacts
2024. Materials Chemistry and Physics, 322, Artklnr.: 129548. doi:10.1016/j.matchemphys.2024.129548 -
Grosselindemann, C.; Reddy, M. J.; Störmer, H.; Esau, D.; Dorn, M.; Bauer, F. M.; Ewald, D.; Wissmeier, L.; Froitzheim, J.; Weber, A.
Impact of CeCo-Coated Metallic Interconnectors on SOCs Towards Performance, Cr-Oxide-Scale, and Cr-Evaporation
2024. Journal of The Electrochemical Society, 171 (5), Art.-Nr.: 054508. doi:10.1149/1945-7111/ad44da -
Sarma, B. B.; Grunwaldt, J.-D.
Operando Spectroscopy to Understand Dynamic Structural Changes of Solid Catalysts
2024. CHIMIA, 78 (5), 288–296. doi:10.2533/chimia.2024.288 -
Enss, A. E.; Plessow, P. N.; Studt, F.
Theoretical investigation of the paring mechanism of the MTO process in different zeolites
2024. Journal of Catalysis, 432, Art.-Nr.: 115363. doi:10.1016/j.jcat.2024.115363 -
Biffar, L.; Benzinger, W.; Pfeifer, P.
A Simplified Approach for Calculating Heat Transfer Coefficients for Fluid Guiding Elements with Alternating Redirections of Flow
2024. Chemie Ingenieur Technik, 96 (8), 1116–1122. doi:10.1002/cite.202300104 -
El Mellas, I.; Samkhaniani, N.; Falsetti, C.; Stroh, A.; Icardi, M.; Magnini, M.
Numerical investigation of bubble dynamics and flow boiling heat transfer in cylindrical micro-pin-fin heat exchangers
2024. International Journal of Heat and Mass Transfer, 228, Art.-Nr.: 125620. doi:10.1016/j.ijheatmasstransfer.2024.125620 -
Doering, M.; Trinkies, L. L.; Kieninger, J.; Kraut, M.; Rupitsch, S. J.; Dittmeyer, R.; Urban, G. A.; Weltin, A.
In Situ Performance Monitoring of Electrochemical Oxygen and Hydrogen Peroxide Sensors in an Additively Manufactured Modular Microreactor
2024. ACS Omega, 9 (17), 19700–19711. doi:10.1021/acsomega.4c02210 -
Dhamo, D.; Kühn, J.; Lüttin, S.; Rubin, M.; Dittmeyer, R.
Coupling the high-temperature Fischer–Tropsch synthesis and the skeletal isomerization reaction at optimal operation conditions in the Power-to-Fuels process route for the production of sustainable aviation gasoline
2024. Sustainable Energy & Fuels, 8 (9), 2094–2103. doi:10.1039/d3se01351k -
Crone, M.; Trinkies, L. L.; Dittmeyer, R.; Türk, M.
Deposition of Pd, Pt, and PdPt Nanoparticles on TiO Powder Using Supercritical Fluid Reactive Deposition: Application in the Direct Synthesis of H O
2024. Molecules, 29 (9), Art.-Nr.: 2142. doi:10.3390/molecules29092142 -
Metzger, D. F.; Klahn, C.; Dittmeyer, R.
A Simplified Design Method for the Mechanical Stability of Slit-Shaped Additively Manufactured Reactor Modules
2024. Designs, 8 (3), Art.-Nr.: 41. doi:10.3390/designs8030041 -
Oppel, N.; Röse, P.; Heuser, S.; Prokein, M.; Apfel, U.-P.; Krewer, U.
Unveiling the kinetics of CO reduction in aprotic electrolyte: The critical role of adsorption
2024. Electrochimica Acta, 490, Art.-Nr.: 144270. doi:10.1016/j.electacta.2024.144270 -
Tusini, E.; Casapu, M.; Zimina, A.; Doronkin, D. E.; Störmer, H.; Barthe, L.; Belin, S.; Grunwaldt, J.-D.
Structural Changes of Ni and Ni–Pt Methane Steam Reforming Catalysts During Activation, Reaction, and Deactivation Under Dynamic Reaction Conditions
2024. ACS Catalysis, 7463–7477. doi:10.1021/acscatal.3c05847 -
Scotti, N.; Borsacchi, S.; Monti, S.; Zimina, A.; Evangelisti, C.; Geppi, M.; Dambruoso, P.; Barcaro, G.; Bossola, F.; Dal Santo, V.; Ravasio, N.
Spectroscopic and theoretical investigation of Brønsted acid sites in amorphous mixed Zr-Si oxide nanoparticles
2024. Journal of Alloys and Compounds, 992, Article no: 174545. doi:10.1016/j.jallcom.2024.174545 -
Spielmann, J.; Braig, D.; Streck, A.; Gustmann, T.; Kuhn, C.; Reinauer, F.; Kurnosov, A.; Leubner, O.; Potapkin, V.; Hasse, C.; Deutschmann, O.; Etzold, B. J. M.; Scholtissek, A.; Kramm, U. I.
Exploring the oxidation behavior of undiluted and diluted iron particles for energy storage: Mössbauer spectroscopic analysis and kinetic modeling
2024. Physical Chemistry Chemical Physics, 26 (17), 13049–13060. doi:10.1039/d3cp03484d -
Münzer, P.; Arnold, U.; Sauer, J.
Process Design for the Directly Coupled Production of Methanol and Formaldehyde Based on CO
2024. Chemie Ingenieur Technik, 96 (6), 819–825. doi:10.1002/cite.202300183 -
Hirth, T.; Jordan, T.
Wasserstoff [Editorial]
2024. Chemie Ingenieur Technik, 96 (1-2), 3–3. doi:10.1002/cite.202470102 -
Toprak, M.; Samkhaniani, N.; Stroh, A.
Drop rebounding on heated micro-textured surfaces
2024. International Journal of Heat and Mass Transfer, 227, Artk.Nr.: 125498. doi:10.1016/j.ijheatmasstransfer.2024.125498 -
Eberhard, A.; Metni, H.; Fahland, G.; Stroh, A.; Friederich, P.
Actively learning costly reward functions for reinforcement learning
2024. Machine Learning: Science and Technology, 5 (1), Art.-Nr.: 015055. doi:10.1088/2632-2153/ad33e0 -
Das, S.; Stuckelberger, M. E.; Pottbacker, J.; Jakobtorweihen, S.; Schroer, C. G.; Horn, R.; Sheppard, T. L.
Quantitative Chemical Mapping of Pt/Rh Gauze Catalysts for Ammonia Oxidation using Resonant X-ray Tomography
2024. The Journal of Physical Chemistry C, 128 (12), 5053–5063. doi:10.1021/acs.jpcc.4c00041 -
Mokashi, M.; Shirsath, A. B.; Çelik, A.; Lott, P.; Müller, H.; Tischer, S.; Maier, L.; Bode, J.; Schlereth, D.; Scheiff, F.; Flick, D.; Bender, M.; Ehrhardt, K.; Deutschmann, O.
Methane pyrolysis in packed bed reactors: Kinetic modeling, numerical simulations, and experimental insights
2024. Chemical Engineering Journal, 485, Art.-Nr.: 149684. doi:10.1016/j.cej.2024.149684 -
Hagg, D.; Eifert, A.; Troßmann, T.; Frohnapfel, B.; Marschall, H.; Wörner, M.
Numerical study of liquid imbibition and contact line pinning in a sealing gap for corrosion protection of metal housings
2024. Progress in Computational Fluid Dynamics, An International Journal, 24 (2), 65 – 77. doi:10.1504/PCFD.2024.137058 -
Yang, M.; Yu, J.; Zimina, A.; Sarma, B. B.; Grunwaldt, J.-D.; Zada, H.; Wang, L.; Sun, J.
Inside Back Cover: Unlocking a Dual‐Channel Pathway in CO Hydrogenation to Methanol over Single‐Site Zirconium on Amorphous Silica
2024. Angewandte Chemie International Edition, 63 (4). doi:10.1002/anie.202319538 -
Rosmini, C.; Pazos Urrea, M.; Tusini, E.; Indris, S.; Kovacheva, D.; Karashanova, D.; Kolev, H.; Zimina, A.; Grunwaldt, J.-D.; Rønning, M.; Dimitrov, M.; Popova, M.
Unveiling the synergistic effects of pH and Sn content for tuning the catalytic performance of Ni^0/Ni_{x}Sn_{y} intermetallic compounds dispersed on Ce-Zr mixed oxides in the aqueous phase reforming of ethylene glycol
2024. Applied catalysis / B, 350, Art.Nr.: 123904. doi:10.1016/j.apcatb.2024.123904 -
Pazos Urrea, M.; Meilinger, S.; Herold, F.; Gopakumar, J.; Tusini, E.; De Giacinto, A.; Zimina, A.; Grunwaldt, J.-D.; Chen, D.; Rønning, M.
Aqueous Phase Reforming over Platinum Catalysts on Doped Carbon Supports: Exploring Platinum–Heteroatom Interactions
2024. ACS Catalysis, 14 (6), 4139–4154. doi:10.1021/acscatal.3c05385 -
Neukum, D.; Saraçi, E.; Wüst, D.; Raj Lakshmi Nilayam, A.; Sharma, S.; Grunwaldt, J.-D.
Rational process design for the efficient oxidation of crude HMF-solution using AuPd/C catalysts
2024. Catalysis Today, 432, Article no: 114615. doi:10.1016/j.cattod.2024.114615 -
Zhang, Q.; Li, Y.; Otroshchenko, T.; Kondratenko, V. A.; Wu, K.; Fedorova, E. A.; Doronkin, D. E.; Bartling, S.; Lund, H.; Jiang, G.; Kondratenko, E. V.
The enhancing effect of Co on propane non-oxidative dehydrogenation over supported Co/ZrO catalysts
2024. Journal of Catalysis, 432, Art.-Nr.: 115440. doi:10.1016/j.jcat.2024.115440 -
Huang, J.; Klahn, M.; Tian, X.; Bartling, S.; Zimina, A.; Radtke, M.; Rockstroh, N.; Naliwajko, P.; Steinfeldt, N.; Peppel, T.; Grunwaldt, J.-D.; Logsdail, A. J.; Jiao, H.; Strunk, J.
Fundamental structural and electronic understanding of palladium catalysts on nitride and oxide supports
2024. Angewandte Chemie International Edition, Art.Nr.: e202400174. doi:10.1002/anie.202400174 -
Smitshuysen, T. E. L.; Lützen, M.; Zimina, A.; Sheppard, T. L.; Jakobsen, H. H.; Chorkendorff, I.; Damsgaard, C. D.
Using CoCu Ga/SiO to identify stability-issues in ethanol-selective Co-Cu alloyed catalysts in carbon monoxide hydrogenation
2024. Applied Catalysis A: General, 675, 119636. doi:10.1016/j.apcata.2024.119636 -
Neukum, D.; Lakshmi Nilayam, A. R.; Ludwig, M. E.; Vadarlis, A. A.; Grunwaldt, J.-D.; Saraçi, E.
Continuous flow oxidation of HMF using supported AuPd-alloy
2024. Catalysis Science & Technology, 14 (8), 2130–2138. doi:10.1039/D3CY01722B -
Rodrigues Niquini, G.; Lacerda de Oliveira Campos, B.; Herrera Delgado, K.; Pitter, S.; Sauer, J.
Experimental study and comprehensive kinetic modeling of the direct dimethyl ether synthesis on Cu/ZnO/ZrO₂ and H-FER-20
2024. Chemical Engineering Journal, 480, Art.-Nr.: 147968. doi:10.1016/j.cej.2023.147968 -
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Zhang, Y.; Yadav, R.; Omrani, A.; Fjeld, M.
A novel augmented reality system to support volumetric visualization in industrial process tomography
2021. IHCI GET 2021 Proceedings. Proceedings of the IADIS International Conference Interfaces and Human Computer Interaction Proceedings of the IADIS International Conference Game and Entertainment Technologies. Hrsg.: K. Blashki, 3–9, IADIS Press -
Hofele, J.; Gandert, J.; Link, G.; Jelonnek, J.
Modelling the thermal runaway during the stabilization phase of the carbon fiber production using microwave heating
2021. AMPERE 2021: 18th International Conference on Microwave and High-Frequency Applications: 13th -16th September 2021, Gothenburg, Sweden, 234, Chalmers University of Technology (Chalmers) -
Neumaier, D.; Link, G.; Jelonnek, J.
Influence of cavity size and material properties on the uniformity of dielectric heating using distributed sources and novel solid-state microwave amplifiers
2021. AMPERE 2021: 18th International Conference on Microwave and High-Frequency Applications: 13th -16th September 2021, Gothenburg, Sweden, 155, Chalmers University of Technology (Chalmers) -
Togashi, M. M.; Perdomo, C. P. F.; Link, G.; Kiminami, R. H. G. A.
Effect of initial particle size of the hematite on microwave sintering kinetics at 30 GHz
2021. AMPERE 2021 Proceedings, 8th International Conference on Microwave and High - Frequency Applications, 13th - 16th September 2021, 102, Chalmers University of Technology (Chalmers) -
Yadav, R.; Omrani, A.; Vauhkonen, M.; Link, G.; Lähivaara, T.
Complex-permittivity estimation of a polymer foam using microwave tomography for the application of microwave drying
2021. AMPERE 2021 Proceedings, 8th International Conference on Microwave and High - Frequency Applications, 13th - 16th September 2021, 42, Chalmers University of Technology (Chalmers) -
Li, N.; Link, G.; Jelonnek, J.
A compact quarter wavelenght filter for 3D microwave printing of continuous fiber reinforced polymers
2021. AMPERE 2021: 18th International Conference on Microwave and High-Frequency Applications: 13th -16th September 2021, Gothenburg, Sweden, 1, Chalmers University of Technology (Chalmers) -
Omrani, A.; Yadav, R.; Link, G.; Jelonnek, J.
A time-reversal imaging algorithm for localization and moisture level detection in the polymer foam in an industrial microwave drying system
2021. AMPERE 2021 Proceedings, Chalmers University of Technology (Chalmers) -
Li, N.; Link, G.; Ma, J.; Jelonnek, J.
LiDAR Based Multi-Robot Cooperation for the 3D Printing of Continuous Carbon Fiber Reinforced Composite Structures
2021. Advances in Manufacturing Techno – Proceedings of the 18th International Conference on Manufacturing Research, incorporating the 35th National Conference on Manufacturing Research, 7–10 September 2021, University of Derby, Derby, UK. Ed.: M. Shafik, 125–132, IOS Press. doi:10.3233/ATDE210024 -
Omrani, A.; Yadav, R.; Link, G.; Vauhkonen, M.; Lahivaara, T.; Jelonnek, J.
A Combined Microwave Imaging Algorithm for Localization and Moisture Level Estimation in Multilayered Media
2021. 2021 15th European Conference on Antennas and Propagation (EuCAP), 22-26 March 2021, Düsseldorf, Germany, Institute of Electrical and Electronics Engineers (IEEE). doi:10.23919/EuCAP51087.2021.9411327 -
Yadav, R.; Omrani, A.; Vauhkonen, M.; Link, G.; Lähivaara, T.
Microwave Tomography for Moisture Level Estimation Using Bayesian Framework
2021. 2021 15th European Conference on Antennas and Propagation (EuCAP), Düsseldorf, 22. - 26. März 2021, Düsseldorf, Institute of Electrical and Electronics Engineers (IEEE). doi:10.23919/EuCAP51087.2021.9411109 -
Omrani, A.; Link, G.; Jelonnek, J.
A Multistatic Uniform Diffraction Tomographic Algorithm for Real-Time Moisture Detection
2021. 2020 IEEE Asia-Pacific Microwave Conference (APMC), 437–439, Institute of Electrical and Electronics Engineers (IEEE). doi:10.1109/APMC47863.2020.9331603
Finished Dissertations
Synthesis gas production via CO conversion with in-situ CO
2024, September 12. Karlsruher Institut für Technologie (KIT). doi:10.5445/IR/1000174128
Direkte katalytische Hydrierung von CO2 zu langkettigen Kohlenwasserstoffen - Kinetik, Selektivität und Skalierung. PhD dissertation
2024, July 29. Karlsruher Institut für Technologie (KIT). doi:10.5445/IR/1000172552
Untersuchung der innermotorischen Stickstoffdioxid- und Formaldehydbildung bei Magerbrennverfahren mit regenerativen Kraftstoffen. PhD dissertation
2024, June 24. Logos Verlag Berlin
Multistatic Uniform Diffraction Tomography and Time-Reversal Algorithms for Microwave Imaging of Multilayered Media. PhD dissertation
2024, June 4. Karlsruher Institut für Technologie (KIT). doi:10.5445/IR/1000171229
Multiskalensimulation eines Bio-Mikroreaktors mit immobilisierten Enzymkaskaden. PhD dissertation
2024, June 13. Karlsruher Institut für Technologie (KIT). doi:10.5445/IR/1000170904
Untersuchungen zur Direktsynthese von Wasserstoffperoxid in mikrostrukturierten Membranreaktoren. PhD dissertation
2024, July 17. Karlsruher Institut für Technologie (KIT). doi:10.5445/IR/1000169011
Multi-Physics Modelling towards the Stabilization of PAN Fibers with Microwaves Based on Experimental Data. PhD dissertation
2024. doi:10.5445/KSP/1000168942
Multi-Physics Modelling towards the Stabilization of PAN Fibers with Microwaves Based on Experimental Data. PhD dissertation
2024, February 23. Karlsruher Institut für Technologie (KIT). doi:10.5445/IR/1000168701
Experimentelle und theoretische Untersuchung der gas/flüssig-Phasentrennung in Mikrokontaktoren. PhD dissertation
2024, April 18. Karlsruher Institut für Technologie (KIT). doi:10.5445/IR/1000167096
Heterogen katalysierte Insertion von Kohlenstoffmonoxid in sauerstoffhaltige organische Verbindungen. PhD dissertation
2024, April 19. Karlsruher Institut für Technologie (KIT). doi:10.5445/IR/1000165194
Eine modellprädiktive Regelung zur holistischen Minimierung dieselmotorischer Emissionen im Realfahrbetrieb. PhD dissertation
2024, January 15. Cuvillier Verlag
Modellbasierte Methoden zur transienten Optimierung von Antriebssystemen. PhD dissertation
2023, December 20. Karlsruher Institut für Technologie (KIT). doi:10.5445/IR/1000165534
Intensivierung des Stofftransports zweiphasiger Reaktionssysteme durch strukturierte Reaktoren: Einsatz ortsaufgelöster in-situ Analytik. PhD dissertation
2023, October 27. Verlag Dr. Hut
Intensified Process Technologies for the Single-Step Polycondensation of Saccharides. PhD dissertation
2023, September 28. Karlsruher Institut für Technologie (KIT). doi:10.5445/IR/1000162580
Optimierung von Fotokatalysatoren und Fotoreaktoren für die Synthese solarer Kraftstoffe = Optimizing photocatalysts and photoreactors for solar fuel synthesis. PhD dissertation
2023, September 21. Karlsruher Institut für Technologie (KIT). doi:10.5445/IR/1000162170
Integrated Microreactor System for One-stage Synthesis of Dimethyl Ether from Carbon Dioxide and Hydrogen. PhD dissertation
2023, August 22. Karlsruher Institut für Technologie (KIT). doi:10.5445/IR/1000161161
Unravelling structural dynamics in Cu/ZnO-based methanol catalysts for future Power-to-Liquid applications. PhD dissertation
2023, May 25. Karlsruher Institut für Technologie (KIT)
Multiscale modeling of the methanol synthesis: from surface reaction kinetics to techno-economic analysis. PhD dissertation
2023, May 8. Karlsruher Institut für Technologie (KIT). doi:10.5445/IR/1000158433
Charakterisierung des Alterungsverhaltens von Pyrolyseöl sowie dessen Stabilisierung und Konditionierung mit Ethanol und verdichtetem CO₂. PhD dissertation
2023, February 14. Karlsruher Institut für Technologie (KIT). doi:10.5445/IR/1000155830
Semi-mechanistic, data-based, and hybrid models: A comprehensive comparison on the example of the direct DME synthesis from CO2-rich synthesis gas. PhD dissertation
2023, February 1. Karlsruher Institut für Technologie (KIT). doi:10.5445/IR/1000155261
Energy-efficient, scalable and modular industrial microwave applicator for high temperature alkaline hydrolysis of PET. PhD dissertation
2023. KIT Scientific Publishing. doi:10.5445/KSP/1000131787
Theoretical Insights into the Light Alkanes Dehydrogenation and Aldehydes Hydrogenation on Transition Metal and Metal Oxide Surfaces. PhD dissertation
2022, December 8. Karlsruher Institut für Technologie (KIT). doi:10.5445/IR/1000152395
Entstehung kleiner Ölaerosolpartikel am Kurbeltrieb eines schweren Nutzfahrzeugmotors mit Fokus auf der Kolben-Kolbenring-Laufbuchsen-Gruppe. PhD dissertation
2022, September 8. Logos Verlag Berlin
Hierarchical Multiscale Modelling of CoCu Catalyst in CO Hydrogenation : Bridge the Gap between Microscopic and Mesoscopic Systems. PhD dissertation
2022, October 12. Karlsruher Institut für Technologie (KIT). doi:10.5445/IR/1000150313
Intermetallische Verbindungen als Katalysatoren für die Semi-Hydrierung von Acetylen in mikrostrukturierten Reaktoren. PhD dissertation
2022, July 29. Karlsruher Institut für Technologie (KIT). doi:10.5445/IR/1000149045
Demonstration und Evaluation der kontinuierlichen und heterogenkatalysierten Synthese von Oxymethylendimethylethern (OME) aus Dimethylether und Trioxan. PhD dissertation
2022, March 3. Karlsruher Institut für Technologie (KIT). doi:10.5445/IR/1000143343
Synthese und Charakterisierung bimetallischer Nanopartikel in ionischen Flüssigkeiten für katalytische Anwendungen. PhD dissertation
2021. Ruprecht-Karls-Universität Heidelberg
Compact Microstructured Reactors for Decentralized Methanation of CO
2021, December 17. Karlsruher Institut für Technologie (KIT). doi:10.5445/IR/1000141228
Zellfreie Biokatalyse im Mikrofluidsystem für die biotechnologische Produktion von chemischen Grundbausteinen. PhD dissertation
2021, December 14. Verlag Dr. Hut
Additively manufactured permeable-dense composites and its applications in microstructured reactors. PhD dissertation
2021, December 8. Karlsruher Institut für Technologie (KIT). doi:10.5445/IR/1000140785
Theoretical Studies of Catalyst Structure and Kinetics in the MTO Process. PhD dissertation
2021, September 17. Karlsruher Institut für Technologie (KIT). doi:10.5445/IR/1000137528
Theoretical studies of dehydration reactions and the aromatic cycle of the MTO process. PhD dissertation
2021, March 30. Karlsruher Institut für Technologie (KIT)
Dezentrale Synthese strombasierter flüssiger Kraftstoffe über die Fischer-Tropsch Route. PhD dissertation
2021, March 2. Karlsruher Institut für Technologie (KIT). doi:10.5445/IR/1000129949
Energy-efficient, scalable and modular industrial microwave applicator for high temperature alkaline hydrolysis of PET. PhD dissertation
2021, February 10. Karlsruher Institut für Technologie (KIT). doi:10.5445/IR/1000129260
Reaktorkonzepte zur Dehydrierung von cyclischen Kohlenwasserstoffen zur Wärme- und Wasserstoffspeicherung. PhD dissertation
2021, February 4. Karlsruher Institut für Technologie (KIT). doi:10.5445/IR/1000129160
Dynamische Untersuchungen bei intensivierter Fischer-Tropsch Synthese. PhD dissertation
2021, February 1. Karlsruher Institut für Technologie (KIT). doi:10.5445/IR/1000128675
Direktsynthese von Wasserstoffperoxid im mikrostrukturierten Membranreaktor. PhD dissertation
2021, January 11. Karlsruher Institut für Technologie (KIT). doi:10.5445/IR/1000127910